Dietoksykarbonilmetil ve 2-dimetilaminoetilsulfanil substituentlerini içeren metalliftalosiyaninlerin sentezi

Abstract

ÖZET Bu çalışmada, 4-(2-dimetilaminoetilsulfanil)ftalonitril, Dietil 3,4-disiyanofenil malonat, 2/346/17-di-(4-dimetilaminoetilsulfanil)-9/10,23/24-di-(detoksikarbonilmetil) ftalosiyaninato kobalt(II), 2/3,1 6/1 7-di(dimetilaminoetilsulfanil)-9/l 0,23/24 di (dietoksikarbonilmetil) ftalosiyaninato nikel(II), 2/3,1 6/1 7-di(dimetilaminoetilsulfanil)- 9/10,23/24 di(dietoksikarbonilmetil) ftalosiyaninato çinko(II), tetra (dietoksykarbonilmetil) ftalosiyaninato kobalt (II), tetra(dietoksykarbonilmetil) ftalosiyaninato çinko(II), yedi bileşik sentezlendi. Bu bileşiklerin yapılan UV, İR, 'H-NMR spektrumlan ile karakterize edilmiştir. Anahtar Kelimeler : Ftalosiyanin; Metalli Ftalosiyanin; Siklotetramerizasyon; Makrosiklik; Asimetrik Ftalosiyanin. IV

SUMMARY In this study, 4-(2-dimethylaminoethylsulfanyl)phtalonitril, Diethyl 3,4- dicyanophenyl malonate,. 2/3,1 6/1 7-di-(4-dimethylaminoethylsulfanyl)-9/l 0,23/24 di(diethoxicarbonylmethyl) phthalocyaninato cobalt(II), 2/3,16/17- di(dimethylaminoethylsulfanyl)-9/10,23/24-di-(diethoxicarbonylmethyl) phthalocyaninato nickel(II), 2/3,16/17-di-(dimethylaminoethylsulfanyl)-9/10,23/24 di(diethoxicarbonylmethyl) phthalociyaninato zinc(II), tetra(diethoxycarbonylmethyl) phthalocyaninato cobalt(II), tetra(diethoxycarbonylmethyl) phthalocyaninato zinc(II), compounds were synthesized. The structure of these compounds have been characterized by UV, IR ^H-NMR, spectra. Keywords : Phthalocyanine; Metallo Phthalocyanine; Cyclotetramerization; Macrocycle ;Unsymetric Phthalocyanine. V