1-naftoksi, 1-naftil amino ve 1-naftil sübstitüe siklotrifosfazen bileşiklerinin sentezi ve karakterizasyonu

Abstract

oz Yüksek Lisans Tezi 1-NAFTOKSI, 1-NAFTIL AMINO VE 1-NAFTİL SÜBSTITUE SIKLOTRIFOSFAZEN BİLEŞİKLERİNİN SENTEZİ VE KARAKTERİZASYONU Oğuzhan HALCİ Harran Üniversitesi Fen Bilimleri Enstitüsü Kimya Anabilim Dalı Danışman Yrd. Doç. Dr. Fatih ASLAN Yıl: 2005, Sayfa: 33 Hek2aklorosiklotrifosfazen[(NPCl2)3](I) ile 1-naftol ve 1-naftilamino bileşiklerinin reaksiyonları THF ortamında 65 °C'de argon atmosferinde gerçekleştirildi. (NPC12)3 ile 1-naftil amino reaksiyonundan geminal disübstitüe 2,2-di(l-naftilamino)-4,4,6,6-tetraklorosiklotrifosfazen(II), 1-naftolla reaksiyonundan tam süsbtiüe hekza(l-naftoksi)siklotrifosfazen(III) sentezlendi. 1-naftilmagnezyum bromür hazır olarak elde edilemediğinden dolayı 1-naftil süsbtitüe siklotrifosfazen izole edilemedi. II ve III yapılarının aydınlatılması İR, ('H, 13C, 3IP) NMR ve elementel analiz ile yapıldı. ANAHTAR KELİMELER: Fosfazenler, siklotrtifosfazen, 1-naftilamino, 1-naftol

ABSTRACT MSc Thesis SYNTHESIS AND CHARACTERIZATION OF 1-NAPHTOXY, 1-NAPHTYL AMINO AND 1-NAPHTYL SUBSTITUTED CYCLOTRIPHOSPHAZENE COMPOUNDS Oğuzhan HALCİ Harran University Graduate School of Natural and Applied Science Department of Chemistry Supervisor: Assist. Prof. Dr. Fatih ASLAN Year: 2005, Page: 33 The reactions of hexachlorocyclotriphosphazene[(NPCl2)3](I) with 1-naphtyl amine and 1-naphthol reagents were performed in THF solvent at 65 °C under argon atmosphere. Geminal 2,2-di(l-naphtyI amino)-4,4,6,6-tetrachclorocyclotriphosphazene(II) was synthesized by the reaction of I with 1- naphtyl amine. Fully substituted hexa(l-naphtoxy)cyclotriphosphazene(III) was synthesized by the reaction of I with 1-naphtyl amine. 1-naphtyl substituted cyclotriphosphazene was not isolated, because 1-naphtylmagnesium bromide was not obtained as prepared commercially. The characterization of structures of II and III was carried out by 'H, 13C and 3IP NMR spectroscopy, infrared and elemental analysis. KEY WORDS: Phosphazenes, cyclotriphosphazenes, 1-naphtyl amine, 1-naphthol 11