Karboksil grubu taşıyan organik bileşiklerden radikalik yoldan dekarboksilasyon reaksiyonlarının incelenmesi
| dc.contributor.advisor | Gülten, Şirin | |
| dc.contributor.author | Tuntaş, Hamdi | |
| dc.date.accessioned | 2021-05-07T09:04:05Z | |
| dc.date.available | 2021-05-07T09:04:05Z | |
| dc.date.submitted | 2002 | |
| dc.date.issued | 2018-08-06 | |
| dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/604814 | |
| dc.description.abstract | oz Bu çalışmada N-hidroksipiridin-2-tiyonla elde edilen karboksilik asit esterlerinin radikalik dekarboksilasyonu incelendi. Bu amaçla başlangıç maddesi olarak 2-etilhekzanoik asit ve benzoik asit seçildi İlk olarak, benzoik asit benzoilklorüre dönüştürüldü. Ardından N-hidroksipiridin-2- tiyon sodyum tuzu ile esterine dönüştürülüp, AIBN (2,2,-azobisizobutironitril) ve Bu3SnH (tribütilkalayhidrür) ile radikalik dekarboksilasyon reaksiyonu gerçekleştirildi. Bazı ürünlerin spektroskopik analizleri yapıldı. 2-Etilheksanoik asitin radikalik dekarboksilasyon reaksiyonu uygulanamadı. Anahtar Kelimeler: Serbest radikal radikalik dekarboksilasyon, N- hidroksipiridin-2-tiyon esterleri, AlBN ve BU3SnH. | |
| dc.description.abstract | ABSTRACT In this study, radical decarboxylation of carboxylic acid esters derived from N- hydroxypyridine-2-thione was investigated. 2-Ethylhexanoic acid and benzoic acid were chosen as starting materials. Firstly, benzoic acid was converted to benzoylchloride, and then the chloride was converted to ester with jV-hyclroxypyridine-2-thione sodium salt. The radical reaction was carried out with AIBN (2,2'-azobis/sobutyronitrile) and Bu3SnH (tributyltinhydride). Some products were analysed by spectroscopic methods. The radical decarboxylation of 2- ethylhexanoic acid couldn't be applied. Keywords: Free radical, radical decarboxylation, A/-hydroxypyridine-2-thione esters, AIBN and BusSnH. II | en_US |
| dc.language | Turkish | |
| dc.language.iso | tr | |
| dc.rights | info:eu-repo/semantics/embargoedAccess | |
| dc.rights | Attribution 4.0 United States | tr_TR |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Kimya | tr_TR |
| dc.subject | Chemistry | en_US |
| dc.title | Karboksil grubu taşıyan organik bileşiklerden radikalik yoldan dekarboksilasyon reaksiyonlarının incelenmesi | |
| dc.title.alternative | The Investigation of decarboxylation reaction of including carboxylic acid functional group of organic by radical method | |
| dc.type | masterThesis | |
| dc.date.updated | 2018-08-06 | |
| dc.contributor.department | Diğer | |
| dc.subject.ytm | Esterification | |
| dc.subject.ytm | Carboxylic acids | |
| dc.subject.ytm | Free radicals | |
| dc.subject.ytm | Decarboxylation | |
| dc.identifier.yokid | 129076 | |
| dc.publisher.institute | Fen Bilimleri Enstitüsü | |
| dc.publisher.university | ÇANAKKALE ONSEKİZ MART ÜNİVERSİTESİ | |
| dc.identifier.thesisid | 121532 | |
| dc.description.pages | 55 | |
| dc.publisher.discipline | Diğer |
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