5.5-dibrono-bisiklo [2.1.0,1.4] pentan ve 2-bromo-3-trimetilsilil siklohekzen`in sentezi ve reaksiyonları
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Abstract
In this work; the synthesis of the 1,2-Cyclopentadieneand 1, 2-CycloheXadiene was worked on. First, 5,5-Dibromobicyclo2.1.01 •4 pentane was synthesized as the startingcompound. It was seen that 1,2-cyclopentadiene has not fformed from the reaction of 5,5-dibromo-bicyclo 2.1.01 •4pentane with CH3L;- and BuLL2-Bromo-3-trimethylsilylcyclohexene was syn-thesized as astar-ting material for the synthesis of 1,2-cyclohexadiene.It has been seen that 1,2-cyclohexadiene forms from thereaction of 2-bromo-3-trimethylsilylcyclohexene wi th florUrbases. Thus, for the synthesis of cyclic allene a new methodwas improved.
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