Nafto (b)siklopropenin katılma reaksiyonları
dc.contributor.advisor | Durucasu, İnci | |
dc.contributor.author | Saraçoğlu, Nurullah | |
dc.date.accessioned | 2020-12-03T14:02:37Z | |
dc.date.available | 2020-12-03T14:02:37Z | |
dc.date.submitted | 1991 | |
dc.date.issued | 2018-08-06 | |
dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/52468 | |
dc.description.abstract | Yapılan kaynak araştırmalarında, nafto[b]siklopropenin 2 değişik dien ve dienofillerle verdiği reaksiyonların yeterince incelenmediği anlaşılmaktadır. Bu nedenle, bu çalışmada ; nafto[b]siklopropenin 2 değişik katılma ürünlerinin sentezlenmesi amaçlandı. Bu amaçla, nafto[b]siklopropen 2 Billups yöntemi kullanılarak 7,7-dikloro-3,4-benzobisiklo[4.1.0]-3-hepten,in 34 dehidrohalojenas- yonu ile elde edildi. Nafto[b]siklopropenin 2 diklorkarben, N-feniltriazolindion, tetrasiyanoetilen, benzin, hidroklorik asit, etanol, asetik asit, benzen, brom, iyot ve hidrojen ile ilgili kaulma ürünleri sentezlendi. Ayrıca nafto[b]siklopropenin diklorkarben ile katılma ürünü, l,l-dikloronafto[b]siklobüten 74, hidroliz edilerek ve indirgenerek nafto[b]siklobütenon 63 ve nafto[b]siklobüten 76 bileşikleri elde edildi. | |
dc.description.abstract | According to literature search, there is no enough investigation about the reactions of naphto[b]cyclopropene 2 with dienes and dienophiles. Therefore, in this study ; it was aimed at synthesizing of different addition products of naphto[b]cyclopropene 2. For this purpose, naphto[b]cyclopropene 2 has been synthesized by dehydrohalogenation of 7,7-dichloro-3,4-benzobicyclo[4.1.0]-3- heptene 34 which is known as Billups method. The reactions of naphto[b]cyclopropene 2 with dichlorocarbene. N-phenyltriazo- linedione, tetracyanoethylene, benzyne, hidrochloric acid, ethanol, acetic acid, benzene, bromine, iodine and hydrogen were carried out respectively and related addition products were obtained. On the other hand, the addition product of naphto[b]cyclopropene with dichlorocarbene, l,l-dicholoronaphto[b]cyclobutene 74 was hydroryzed and naphto[b]cycylobutenone 63 was reduced and naphto[b]- cycylobutene 76 was acquired. | en_US |
dc.language | Turkish | |
dc.language.iso | tr | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.rights | Attribution 4.0 United States | tr_TR |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Kimya | tr_TR |
dc.subject | Chemistry | en_US |
dc.title | Nafto (b)siklopropenin katılma reaksiyonları | |
dc.type | masterThesis | |
dc.date.updated | 2018-08-06 | |
dc.contributor.department | Kimya Anabilim Dalı | |
dc.subject.ytm | Cyclopropene | |
dc.subject.ytm | Nafto (b)syklopropenin | |
dc.identifier.yokid | 17452 | |
dc.publisher.institute | Fen Bilimleri Enstitüsü | |
dc.publisher.university | ATATÜRK ÜNİVERSİTESİ | |
dc.identifier.thesisid | 17452 | |
dc.description.pages | 73 | |
dc.publisher.discipline | Diğer |