1,10- fenantrolin ve azin türevleri içeren bazı geçiş metal komplekslerinin sentezi

Abstract

Bu çalışmada, literatürde kayıtlı olmayan ? -2-pridinaldazinbis(2-(4-fenil)imidazo-[4,5-f][1,10]fenantrolindikloro bakır(II) (7), 2-Pridinaldazin-bakır(II) klorür (2) ile 2-(4-fenil)imidazo-[4,5-f][1,10]fenantrolin (6) bileşiklerinin etanol içerisindeki reaksiyonundan sentezlendi. ? -2-pridinaldazinbis(2-(4-fenil)imidazo-[4,5-f][1,10] fenantrolindikloro nikel(II) (8), 2-Pridinaldazin-nikel(II) klorür (3) ile 2-(4-fenil)imidazo-[4,5-f][1,10]fenantrolin'in (6) etanol içerisindeki reaksiyonundan ve ? -2-pridinaldazinbis(2-(4-fenil)imidazo-[4,5-f][1,10]fenantrolindinitrato kobalt(II) (9), 2-pridinaldazin-kobalt(II) bileşiği ile 2-(4-fenil)imidazo-[4,5-f][1,10]fenantrolin'in (6) Dmf içerisindeki reaksiyonundan sentezlendi. Sentezlenen bileşilerin yapıları IR, MS, TGA, Molar iletkenlik spektral verileri kullanılarak aydınlatıldı.Anahtar Kelimeler: Hidrazin, 2-pridinkarbaldehit, İmidazol, 1,10-Fenantrolin,

In this work, ? -2-pyridinaldazinebis(2-(4-phenyl)imidazo-[4,f][1,10]phenanthroline dichloride copper(II) (7) was sythesized by the reaction of 2-pyridinaldazine-copper (II) chloride (2) with 2-(4-phenil)imidazo-[4,5-f][1,10] phenanthroline (6) in ethanol. ? -2-pyridinaldazinebis(2-(4-phenyl)imidazo-[4,5-f][1,10]phenanthrolinedichloride nickel(II) (8) was prepared by the reaction of 2-pyridinaldazine-nichel (II) chloride (3) with 2-(4-phenil)imidazo-[4,5-f][1,10] phenanthroline (6) in ethanol. ? -2-pyridinaldazinebis(2-(4-phenyl)imidazo-[4,5-f][1,10]phenanthrolinedinitrato cobalt(II) (9) was obtained by the reaction of 2-pyridinaldazine-cobalt (II) nitrato (4) with 2-(4-phenil)imidazo-[4,5-f][1,10] phenanthroline (6) in dimethylformamide. The structures of the synthesized compounds were identified by using IR, MS, TGA, Molar conductivity datas.Key Words:Hydrazine hydrate, Pyridine-2-carboxaldehyd, Imidazole, 1,10- Phenanthroline,