Taç eter grubu ihtiva eden yeni vic-dioksimlerin sentezi, komplekslerinin ve özelliklerinin incelenmesi
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Abstract
Bu çalışmada, literatürde bulunmayan üç adet yeni ligand ve bu ligandların bazı geçişmetalleri ile kompleksleri sentezlendi. Bu ligandlar; anti-4-izopropilanilinfenilaminoglioksim, anti-4-benzilpiperidinfenilaminoglioksim ve N1-(41-Benzo[15-crown-5]naftilaminoglioksim ligandlarıdır. Çalışmanın birinci basamağında;klorofenilaminoglioksim ile 4-izopropilanilin ve 4-benzilpiperidin'in reaksiyonundan anti-4-izopropilanilinfenilaminoglioksim ile anti-4-benzilpiperidinfenilaminoglioksim ligandlarısentezlendi. Ayrıca 41-aminobenzo[15-crown-5] ile 2-naftilkloroglioksim'in reaksiyonusonucu N1-(41-Benzo[15-crown-5]naftilaminoglioksim elde edilmiştir. İkinci basamakta buligandların, Ni(II), Cu(II), Co(II), Cd(II), Zn(II) metal iyonlarıyla kompleksleri elde edildi.Sentezlenen ligandların ve komplekslerin yapıları 1H NMR, 13C-NMR, IR, elementel analiz,mağnetik süsseptibilite teknikleriyle aydınlatıldı. In this study three new ligands and their transition metal complexes were synthesized,which were not yet reported in the literature references. This ligands are; anti-4-isopropylanilinephenylaminoglyoxime, anti-4-benzylpiperidinephenylaminoglyoxime and N1-(41-Benzo[15-crown-5] naphthylaminoglyoxime.In the first part of this work. anti-4-isopropylanilinphenylaminoeglyoxime, anti-4-benzylpiperidinephenylaminoglyoxime were synthesized by the reaction ofcholorophenylaminoglyoxime with 4-isoproplylaniline and 4-benzylpiperidine .In addition tothis, N1-(41-Benzo[15-crown-5]naphthylaminoglyoxime was synthesized by the reaction of4?-Aminobenzo[15-crown-5] and 2-naphthylchloroglyoxime In the second part, their Ni(II),Cu(II), Co(II), Cd(II), Zn(II) complexes were synthesized. This ligands and their complexes?structures were determined with 1H NMR, 13C-NMR, IR, elemental analyses, magnetiksucceptibiliy.
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