Bazı 2(4H-[1,2,4]triazol-3-il-sulfanil)-asetamit türevlerinin sentezi

Abstract

ÖZETYüksek Lisans TeziBAZI 2-(4H-[1,2,4]TR AZOL-3- L-SULFAN L)-ASETAM T TÜREVLER N NSENTEZTekin KESERF rat ÜniversitesiFen Bilimleri EnstitüsüKimya Anabilim Dal2006, Sayfa: V+72Bu çal mada, hidrazit türevlerinin, alkil/aril izotiyosiyanatlar ile reaksiyonundan olu an 1,4-disübstitüe tiyosemikarbazitlerin halkala mas sonucu 1,2,4-triazol halkas ihtiva eden çe itlibile ikler, ve alkil/aril asetamit klorürler sentezlendi. Sentezi gerçekle tirilen 1,2,4-triazol halkasiçeren bile iklerin tiyol formlar ndan K2CO3/aseton ortam nda asetamit klorürlerle etkile tirilerek yeni2-(4H-[1,2,4]Triazol-3-il-sulfanil)-asetamit türevlerine geçildi.Safla t rma i lemleri için, destilasyon ve kristalizasyon yöntemleri kullan ld . Sentezlenenbile iklerin yap lar , FT-IR, 1H-NMR ve 13C-NMR teknikleri ile karakterize edildi.Anahtar Kelimeler : 1,2,4-Triazol, Ditiyokarbamat, Asetamit

ABSTRACTMaster ThesisSYNTHESIS OF SOME COMPOUNDS INCLUDING 2-(4H-[1,2,4]TRIAZOLE-3-YL-SULFANYL)-ACETAMITTekin KESERF rat UniversityGraduate School of Natural and Applied Sciences,Department of Chemistry2006, Page: V+72In this work, various compounds including ring 1,2,4-Triazol were synthesized bycyclization of corresponding 1,4-disubstituted tiyosemicarbazides from the reactions of hydrazidecompounds with alkyl/aryl isotiyocyanates were prepared form of 1,2,4-triazol and derivatives wereprepared by Synthes s of some compounds includ ng 2-(4H-[1,2,4]Triazole-3-yl-sulfanyl)-AcetamitDestilation and crytalization tecniques were used in purification procedures. Structure ofcompounds Synthesized were characterized by, FT-IR, 1H-NMR, and 13C-NMR. tecniques.Keywords: 1,2,4-Triazol, Ditiyocarbamate, Acetamit