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dc.contributor.advisorNecefoğlu, Hacali
dc.contributor.authorKanbay, Bariş
dc.date.accessioned2020-12-06T10:12:06Z
dc.date.available2020-12-06T10:12:06Z
dc.date.submitted2004
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/97250
dc.description.abstractÖZET Bakır(II) arilkarboksilatlarm dokuz adet yeni izonikotinamid kompleksi sentezlenmiştir. [Cu(C7H503)2(C6H6N20)] (I) [Cu(C7H503)2(C6H6N20)2(H20)2] (II) [CuCCvHsOsMCöHö^O^^O)] (IH) [Cu(C7H503)2(C6H6N20)2(H20)2] (H20) (IV) [Cu(C7H6N02)2(C6H6N20)(H20)] (V) [Cu(C7H6N02)2(C6H6N2OXH20)] (VI) [Cu(C7H4N04)2(C6H6N20)2(H20)2] (VII) [Cu(C8H703)2(C6H6N20)(H20)] (VIII) [CU(C7H4C102)2(C6H6N20)2(H20)2] (IX) I, V, VI, Vin ve IX nolu kompleksler için metal : asit : izonikotinamid oranlarının 1:2:1 olduğu saptanarak, komplekslerin kare piramit yapıya sahip olduğu tahmin edilmektedir. II, İÜ, IV, VII nohı kompleksler için metal : asit : izonikotinamid oranlarının 1:2:2 olduğu düşünülmektedir.komplekslerin termik dayanıklılıkları aşağıdaki sırayla artmaktadır. vi<vh<ix<v<iii<iv<ii<viii<i Termik parçalanma sonucunda parçalanma ürünü olarak bütün komplekslerde siyah renkli CuO oluştuğu saptanmıştır. Anahtar kelimeler: Benzoik asit, şahsilik asit, m-hidroksibenzoik asit, p- hidroksibenzoik asit, /»-aminobenzoik asit, /7-aminobenzoik asit, /7-nitrobenzoik asit, /7-metoksibenzoik asit, /7-klorobenzoik asit, izonikotinamid ve bakır(II) kompleksleri.
dc.description.abstractSUMMARY Nine new isonicotinamide complexes of Cu(II) arylcarboxylates has been synthesised: [Cu(C7H503)2(C6H6N20)] (I) [CU(C7H503)2(C6H6N20)2(H20) 2] (E) [CuCC7H503)2(C6H6N20)2(H20)] (III) [Cu(C7H503)2(C6H6N20)2(H20)2] (H20) (TV) [CuCC7H6N02)2(C6H6N20)(H20)] (V) [Cu(C7H6N02)2(C6H6N20)(H20)] (VI) [Cu(C7H4N04)2(C6H6N20)2(H20)2] (VII) [Cu(C8H703)2(C6H6N20)(H20)] (VIII) [C^C^ClO^CeHfiN^^zO),] (DQ It has been presumed that structure of the complexes I, V, VI, VIII and DC were being square pyramidal and the metal : acid : isonicotinamid ratio was 1:2:1. For the complexes of II, III, IV, VII the ratio was also found 1:2:2 and their structure are being thought as octahedrally structured. Thermal stability of complexes are increased as vı<vıı<ıx<v<ııı<rv<ıı<vııı<ı It has been also established that the find product of the thermal decomposition of all complexes is CuO in black colour. Key Words:Benzoic acid, salicylic acid, m-hydroxbenzoic acid, /^?hydroxbenzoic acid, 7W-aminobenzoic acid, p-aminobenzoic acid, p-nitrobenzoic acid, /7-methoxybenzoic acid,p-chlorobenzoik acid, isonicotinamid, copper(n) complexes. VIen_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleBakır (II) arilkarboksilatların izonikotinamid kompleksleri
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentKimya Anabilim Dalı
dc.identifier.yokid168545
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityKAFKAS ÜNİVERSİTESİ
dc.identifier.thesisid151924
dc.description.pages71
dc.publisher.disciplineDiğer


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