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dc.contributor.advisorTağıyev, Babir
dc.contributor.authorAdigüzel, Vedat
dc.date.accessioned2020-12-06T10:11:55Z
dc.date.available2020-12-06T10:11:55Z
dc.date.submitted2004
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/97244
dc.description.abstractÖZET Bu çalışmada, 4-metilbenzoik asitten başlayarak önce 2-sülfoklorür-4- metilbenzoik asit elde edilmiş, sonra bu bileşikten 2-sülfamido-4-metilbenzoik asit, N-(karboksifenil)-sülfamido-4-metilbenzoik asit ve bu bileşiklerin yükseltgenmesinden 2-sülfamidotereftalik ve N-(karboksifenil)-sülfamidotereftalik asitler elde edilmiştir. Elde edilen bileşikler polifosforik asit ortamında siklodehidratasyona uğratılarak, yeni tipli monomerler olan sakkarinkarboksilik asit ve N- (fenilkarboksilik)-sakkarinkarboksilik asitler elde edilmiştir. Çalışmada elde edilen yeni bileşiklerin yapı aydınlatması için mikroanaliz, İR, 'H-NMR, 13C-NMR ve DTA analiz yöntemleri kullanılmıştır. Anahtar kelimeler: Sülfamidotereftalik asit, N-(karboksifenil)- sülfamidotereftalik asitler, N-(karboksifenil)-sakkarinkarboksilik asitler.
dc.description.abstractSUMMARY In this study, firstly 2-sulfonylchloride-4-methylbenzoic acid was synthesized from 4-methylbenzoic acid. Later, out of this compound 2-sulfonylamido-4- methylbenzoic acid and N-(carboxyphenyl)-sulfonylamido-4-methylbenzoic acids were obtained. As a result of oxydationing 2-sulfonylamidoterephthalic acid and N- (carboxyphenyl)-sulfonylamidoterephthalic acids were obtained. The synthesized compounds were put into reaction with polyphosphoric acid. Thus saccharin carboxylic and N-(carboxyphenyl)-saccharincarboxylic acids which are the new type monomers were obtained. In order to identify the new compounds synthesized in the study, microanalysis and spectroscopic methods including IR, 'H-NMR, 13C-NMR, and DTA were used. Key Words: Sulfonylamidoterephthalic acid, N-(carboxyphenyl)- sulfonylamidoterephthalic acid, N-(carboxyphenyl)-saccharincarboxylic acid. VIen_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleSakkarinkarboksilit asitlerin yeni monomer türevlerinin sentezi
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentKimya Anabilim Dalı
dc.identifier.yokid168474
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityKAFKAS ÜNİVERSİTESİ
dc.identifier.thesisid151930
dc.description.pages57
dc.publisher.disciplineDiğer


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