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dc.contributor.advisorNecefoğlu, Hacali
dc.contributor.authorEbebali, Songül
dc.date.accessioned2020-12-06T10:09:11Z
dc.date.available2020-12-06T10:09:11Z
dc.date.submitted2007
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/97160
dc.description.abstractÇinko p-florobenzoat nikotinamid, izonikotinamid ve N,N'-dietilnikotinamid, Çinko p-bromobenzoat N,N'-dietilnikotinamid ve Çinko p-bromobenzoat olmak üzere beş kompleksi ilk defa sentezlenmiştir.[Zn(p-F-C6H4COO)2(C6H6N2O)2(2H2O)] (I)[Zn(p-F-C6H4COO)2(C10H14N2O)2(2H2O)] (II)[Zn(p-F-C6H4COO)2(C6H6N2O)2(2H2O)] (III)[Zn(p-Br-C6H4COO)2(2H2O)] (IV),(VI)[Zn(p-Br-C6H4COO)2(C10H14N2O)2(2H2O)] (V)Çinko p-florobenzoat nikotinamid, izonikotinamid ve N,N'-dietilnikotinamid, Çinko p-bromobenzoat N,N'-dietilnikotinamid oranlarının 1:2:2 oldukları bulunmuştur. Kompleksler oktahedral geometriye sahiptirler. Çinko p-bromobenzoat da ise metal ligand oranı 1:2 olarak belirlenmiştir.Zn(II) p-florobenzoat Nikotinamid/isonikotinamid/N,N'-Dietilnikotinamid içeren kompleksler için susuzlaşma sıcaklıkları II<I<III şeklindedir. Zn(II) p-florobenzoat N,N'-Dietilnikotinamid ve Zn(II) p-bromobenzoat N,N'-Dietilnikotinamid kompleksleri için susuzlaşma sıcaklıkları ise II<V olarak belirlenmiştir. Komplekslerin kararlılık sıralaması ise Zn(II) p-florobenzoat Nikotinamid/isonikotinamid/N,N'-Dietilnikotinamid içeren kompleksler için II<I<III şeklindedir. Zn(II) p-bromobenzoat N,N'-Dietilnikotinamid kompleksleri için kararlılık sıralaması ise II<V olarak belirlenmiştir.
dc.description.abstractFive new complexes of Zinc p-florobenzoates with nicotinamide, isonicotinamide, N,N'-diethylnicotinamide, Zinc p-bromobenzoates with N,N'-diethylnicotinamide, Zinc p-bromobenzoate have been synthesized.[Zn(p-F-C6H4COO)2(C6H6N2O)2(2H2O)] (I)[Zn(p-F-C6H4COO)2(C10H14N2O)2(2H2O)] (II)[Zn(p-F-C6H4COO)2(C6H6N2O)2(2H2O)] (III)[Zn(p-Br-C6H4COO)2(2H2O)] (IV),(VI)[Zn(p-Br-C6H4COO)2(C10H14N2O)2(2H2O)] (V)The rates of metal: p-florobenzoic acid: nicotinamide, isonicotinamide or N,N-diethylnicotinamide in complexes was found as 1:2:2. Synthesized complexes have octahedral geometry. The rates of metal: p-bromobenzoic acid: isonicotinomide was also found as 1:2:2. The rates of metal: p-bromobenzoic acid was determined as 1:2.The thermal behaviour of synthesized complexes were investigated simultaneously by employing thermoanalytical TG-DTG, DTA methods in the temperature range of 20-900ºC in static nitrogen atmosphere. Prepared complexes lose the molecules water of crystallization in one step. Final products are found ZnO, Zn for I, II, III, IV, V, IV.en_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleÇinko p-floro ve p-bromobenzoatların nikotinamid, izonikotinamid ve N,N`-dietilnikotinamid komplekslerinin sentezi ve özellikleri
dc.title.alternativeSentezes and roperties of nicotinamide/izonicotinamide/N,N'-diethylnicotinamide complexes of zinc(II)p-floro/p-bromobenzoates
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentKimya Anabilim Dalı
dc.subject.ytmBenzoates
dc.subject.ytmNicotinamide
dc.subject.ytmIsonicotinamide
dc.identifier.yokid9009746
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityKAFKAS ÜNİVERSİTESİ
dc.identifier.thesisid179300
dc.description.pages80
dc.publisher.disciplineDiğer


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