Show simple item record

dc.contributor.advisorYüksek, Haydar
dc.contributor.authorGül, Hanifi
dc.date.accessioned2020-12-06T10:05:25Z
dc.date.available2020-12-06T10:05:25Z
dc.date.submitted2010
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/97044
dc.description.abstractBu çalışmada, öncelikle çalışma için gerekli olan 9 adet 3-alkil(aril)-4-amino-4,5-dihidro-1H-1,2,4-triazol-5-on bileşiği sentezlenmiştir. Sonra bu bileşiklerin 4-hidroksibenzaldehidin fenilasetil klorür ile muamelesinden elde edilen 4-formilfenil fenilasetat (4-fenilasetoksibenzaldehid) ile reaksiyonları incelenerek 9 adet yeni 3-alkil(aril)-4-(4-fenilasetoksibenzilidenamino)-4,5-dihidro-1H-1,2,4-triazol-5-on bileşiği elde edilmiştir. Sentezlenen yeni bileşiklerin yapıları IR, 1H-NMR, 13C-NMR ve UV spektrum verileri kullanılarak aydınlatılmıştır.Çalışmanın orijinal bölümünde, ikinci olarak sentezlenen 9 yeni 3-alkil(aril)-4-(4-fenilasetoksibenzilidenamino)-4,5-dihidro-1H-1,2,4-triazol-5-on bileşiğinin beş farklı susuz çözücüde (izopropil alkol, tert-butil alkol, aseton, dimetil sulfoksit ve N,N-dimetilformamid) TBAH ile potansiyometrik olarak titrasyonları yapılmış ve yarı-nötralizasyon metodu ile her bir çözücüdeki HNP ve pKa değerleri bulunmuştur.Çalışmada son olarak, sentezlenen yeni bileşiklerin antioksidan özellikleri incelenmiş ve bulunan sonuçlar tartışılmıştır.
dc.description.abstractIn this study, firstly nine 3-alkyl(aryl)-4-amino-4,5-dihydro-1H-1,2,4-triazol-5-one compounds requiring for this study were synthesized. Then, the reaction of these compounds with 4-formylphenyl acetate (4-phenylacetoxybenzaldehyde) which were obtained the reaction of 4-hydroxybenzaldehyde with phenylacetyl chloride, were investigated and nine novel 3-alkyl(aryl)-4-(4-phenylacetoxybenzylidenamino)-4,5-dihydro-1H-1,2,4-triazol-5-one compounds were obtained. In order to identify the nine new compounds synthesized in the study, spestroscopic methods including IR, 1H-NMR, 13C-NMR and UV were used.The second original part of this study, synthesized nine new -alkyl(aryl)-4-(4-phenylacetoxybenzylidenamino)-4,5-dihydro-1H-1,2,4-triazol-5-one compounds were titrated petentiometrically with TBAH in five non-aqueous solvents and HNP and pKa values were determined by main of half neutralization method.Finally, antioxidant properties of synthesized new compounds were investigated and conclusions obtained were discussed.en_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleBazı yeni 4-(4-fenilasetoksibenzilidenamino)-4,5-dihidro-1h-1,2,4-triazol-5-on türevlerinin sentezi, antioksidan ve asitlik özelliklerinin incelenmesi
dc.title.alternativeInvestigated of synthesized, antioxidant and acidity properties of derivatives of some novel 4-(4-phenylacetoxybenzylidenamino)-4,5-dihydro-1h-1,2,4-triazol-5-one
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentKimya Anabilim Dalı
dc.subject.ytm1,2,4-triazole
dc.identifier.yokid376515
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityKAFKAS ÜNİVERSİTESİ
dc.identifier.thesisid294886
dc.description.pages125
dc.publisher.disciplineDiğer


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record

info:eu-repo/semantics/openAccess
Except where otherwise noted, this item's license is described as info:eu-repo/semantics/openAccess