Bazı sikloalkollerle hekzaklorosiklotrifosfazenin reaksiyonlarının incelenmesi
| dc.contributor.advisor | Öztürk, Ali İhsan | |
| dc.contributor.author | Tatsiz, Ramazan | |
| dc.date.accessioned | 2020-12-04T16:31:43Z | |
| dc.date.available | 2020-12-04T16:31:43Z | |
| dc.date.submitted | 2007 | |
| dc.date.issued | 2018-08-06 | |
| dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/92488 | |
| dc.description.abstract | Siklohekzanol, 3-Metil siklohekzanol, 4- Metil siklohekzanol, Siklopentanol ve Siklopropilmetanol'ün oda sıcaklığında, argon atmosferinde ve THF ortamında Na ile alkolatları oluşturuldu. Bualkolatlar ile hekzaklorosiklotrifosfazen[(NPCl2)3](I) oda sıcaklığında, argon atmosferinde, THFortamında reaksiyonlarından tam sübstitüe hekza(siklohekzoksi)siklotrifosfazen(II), Hekza(3-metilsiklohekzoksi)silkotrifosfazen (III) Hekza(4-metil siklohekzoksi) silkotrifosfazen (IV),Hekza(siklopentoksi)siklotrifosfazen(V) ve Hekza(siklopropilmetoksi)siklotrifosfazen(VI) bileşiklerisentezlendi. Bileşiklerin yapıları IR, (1H, 13C, 31P) NMR spektroskopisi yöntemi ile aydınlatıldı.ANAHTAR KELİMELER: Fosfazenler, siklotrtifosfazenler, organofosfazen,hekzaklorosiklotrifosfazen. | |
| dc.description.abstract | The alcoholats were carried out by the reactions of sodium with cyclohexyl alcohol, 3-methylcyclohexyl alcohol, 4-methyl cyclohexyl alcohol, cyclopenthyl alcohol and cyclopropyl emthylalcohol in THF solvent at room temperature under argon atmosphere. The reactions of thesealcoholats with hekzacholorocyclotriphosphazene were performed in THF solvent at roomtemperature. Fully substituted hexa(cyclohexyloxy)cyclotriphosphazene(II), hexa(3-methylcyclohexyloxy)cyclotriphosphazene(III), hexa(4-methyl cyclohexyloxy)cyclotriphosphazene(IV),hexa(cyclopentyloxy)cyclotriphosphazene(V) and hexa(cyclopropylmethyloxy)cyclotriphosphazene(VI) in these reactions were isolated. The structures of the compounds were characterized by 1H, 13Cand 31P NMR spectroscopy, infrared and elemental analysis.KEY WORDS: Phosphazenes, cyclotriphosphazenes, organophosphazene,hexachlorocyclotriphosphazene | en_US |
| dc.language | Turkish | |
| dc.language.iso | tr | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.rights | Attribution 4.0 United States | tr_TR |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Kimya | tr_TR |
| dc.subject | Chemistry | en_US |
| dc.title | Bazı sikloalkollerle hekzaklorosiklotrifosfazenin reaksiyonlarının incelenmesi | |
| dc.title.alternative | Investigation of the reaction of hexachlorocyclotriphosphazene with some cycloalcohols | |
| dc.type | masterThesis | |
| dc.date.updated | 2018-08-06 | |
| dc.contributor.department | Kimya Anabilim Dalı | |
| dc.subject.ytm | Phosphazene | |
| dc.identifier.yokid | 9011300 | |
| dc.publisher.institute | Fen Bilimleri Enstitüsü | |
| dc.publisher.university | HARRAN ÜNİVERSİTESİ | |
| dc.identifier.thesisid | 215821 | |
| dc.description.pages | 37 | |
| dc.publisher.discipline | Diğer |
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