dc.contributor.advisor | Kılıç, Adem | |
dc.contributor.author | Yenilmez, Gönül | |
dc.date.accessioned | 2021-05-07T12:30:15Z | |
dc.date.available | 2021-05-07T12:30:15Z | |
dc.date.submitted | 1997 | |
dc.date.issued | 2018-08-06 | |
dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/621594 | |
dc.description.abstract | ÖZET Bu çalışmada 1,4,7, 10, 13-pentaoksasiklopentadekan-2-metanamin bileşiğinin sentezi gerçekleştirildi. Daha sonra hekzaklorosiklotrifosfazatrien (trimer) ile 1,4,7,10,13- pentaoksasiklopentadekan-2-metanamin'in reaksiyonu ve oluşan ürünlerin yapılan incelendi. Trimer ile 1,4,7, 10, 13-pentaoksasiklopentadekan-2-metanamin'in aşın miktarı alınarak THF içinde ve argon atmosferinde reaksiyon gerçekleştirildi. Trimer ile 1,4,7, 10, 13-pentaoksasiklopentadekan-2-metanamin'in reaksiyonunda %45 verimle altı tane 1,4,7, 10, 13-pentaoksasiklopentadekan-2- metanamin'in bağlandığı trimer türevi hazırlandı. Elde edilen bu bileşiklerin yapılan, kütle, ER, *H NMR, 13C NMR spektrumlarından ve elementel analizden elde edilen bilgilerle açıklandı. | |
dc.description.abstract | . 3 ABSTRACT ^ v In this study, firstly 1,4,7, 10, 13-pentaoxacyclopentadecane-2-memanamine was prepared. And than the reaction of hexachlorocyclotriphosphazatriene with 1,4,7,10,13- pentaoxacyclopentadecane-2-methanamine was investigated and obtained products were elucidated structurely. The trimer was reacted with an excess amount of 1,4,7,10,13- pentaoxacyclopentadecane-2-methanamine in THF and in an argon atmosphere. Trimer and l,4,7,10,13-pentaoxacyclopentadecane-2-methanamine in THF gave 45 % yield which hexasubstituted trimer. This product was investigated structurally via IR, XH NMR, 13C NMR, mass spectra and elemental analysis so the results were given in the manner. | en_US |
dc.language | Turkish | |
dc.language.iso | tr | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.rights | Attribution 4.0 United States | tr_TR |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Kimya | tr_TR |
dc.subject | Chemistry | en_US |
dc.title | Hekzaklorosiklotrifosfozatrien ile pentaoksasiklopentadekan-2-metanamin`in reaksiyonu | |
dc.type | masterThesis | |
dc.date.updated | 2018-08-06 | |
dc.contributor.department | Kimya Ana Bilim Dalı | |
dc.subject.ytm | Hexachlorocyclotriphosphazatriene | |
dc.subject.ytm | Pentaoxacyclopentadecane-2-methanamine | |
dc.identifier.yokid | 66011 | |
dc.publisher.institute | Mühendislik ve Fen Bilimleri Enstitüsü | |
dc.publisher.university | GEBZE YÜKSEK TEKNOLOJİ ENSTİTÜSÜ | |
dc.identifier.thesisid | 66011 | |
dc.description.pages | 56 | |
dc.publisher.discipline | Diğer | |