N-heterosiklik ligandların sentezi ve metal kompleksleri
| dc.contributor.advisor | Şengül, Abdurrahman | |
| dc.contributor.author | Kurt, Özgür | |
| dc.date.accessioned | 2021-05-07T08:32:09Z | |
| dc.date.available | 2021-05-07T08:32:09Z | |
| dc.date.submitted | 2013 | |
| dc.date.issued | 2018-08-06 | |
| dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/597004 | |
| dc.description.abstract | Bu çalışmada iki dişli N-donör heterohalkalı ligandlar olan 2-(piridin-2-il)-1H-benzimidazol (L1), 1-metil-2-(piridin-2-il)-1H-benzmidazol (L2), 2-(piridin-2-il)-1H-naftoimidazol (L3), 6-(1H-benzimidazol-2-il)piridin-2-ol (L4), 6-(1-metil-1H-benzimidazol-2-il)piridin-2-ol (L5), 6-(naftoimidazol-2-il)piridin-2-ol (L6), N-propansulton-2-(piridin-2-il)-1H-benzimidazol (L7) ligandları sentezlenmiştir. Bu ligandların d8 iyonları olan platin(II) ve paladyum(II) ile olan kare düzlem kompleksleri sentezlenmiştir.Sentezlenen bu bileşiklerin yapıları 1H-NMR, FT-IR ve LC-MS teknikleriyle aydınlatılmıştır. | |
| dc.description.abstract | In the present study, bidentate N-donor heterocyclic ligands, 2-(2-pyridine-2-yl)-1H-benzimdiazole (L1), 1-methyl-2-(pyridine-2-yl)-1H-benzimidazole (L2), 2-(pyridine-2-yl)-1H-naphthobenzimidazole (L3), 6-(1H-benzimdazole-2-yl)pyridine-2-ol (L4), 6-(1-methyl-1H-benzimidazole-2-yl)pyridine-2-ol (L5), 6-(naphthoimidazole-2-yl)pyridine-2-ol (L6), N-(propanesultone-2-(pyridine-2-yl)-1H-benzimidazole (L7) have been synthesized. The square-planar metal complexes of these novel ligands with d8 ions such as platinum(II) and palladium(II) have been prepared.The synthesized compounds have been characterized by 1H NMR, FT-IR and LC-MS. | en_US |
| dc.language | Turkish | |
| dc.language.iso | tr | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.rights | Attribution 4.0 United States | tr_TR |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Kimya | tr_TR |
| dc.subject | Chemistry | en_US |
| dc.title | N-heterosiklik ligandların sentezi ve metal kompleksleri | |
| dc.title.alternative | Synthesis and metal complexes of N-heterocyclic ligands | |
| dc.type | doctoralThesis | |
| dc.date.updated | 2018-08-06 | |
| dc.contributor.department | Kimya Ana Bilim Dalı | |
| dc.identifier.yokid | 10023322 | |
| dc.publisher.institute | Fen Bilimleri Enstitüsü | |
| dc.publisher.university | BÜLENT ECEVİT ÜNİVERSİTESİ | |
| dc.identifier.thesisid | 355389 | |
| dc.description.pages | 190 | |
| dc.publisher.discipline | Diğer |
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