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dc.contributor.advisorSoykan, Cengiz
dc.contributor.authorÖzentürk, İsmail
dc.date.accessioned2021-05-07T08:25:08Z
dc.date.available2021-05-07T08:25:08Z
dc.date.submitted2011
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/596601
dc.description.abstractBu çalışmada, N,N'-dipropiyonitril metakrilamit (DPMAAm) monomeri 0-5 oC'de trietilamin yanında N,N'-iminodipropiyonitril ile metakriloilklorürden sentezlendi. Monomerin yapısı FTIR, 1H-NMR ve 13C-NMR spektroskopik teknikleri kullanılarak karakterize edildi. DPMAAm'nin stiren (St) ve p-klormetilen stiren (ClM-St) ile değişik oranlardaki kopolimerleri 1,4-dioksan çözeltisinde %1 oranında AIBN başlatıcısı kullanılarak 70 oC'de %10'un altındaki dönüşümlerde hazırlandı. Kopolimer bileşimleri elementel analiz ile belirlendi. Monomer reaktivite oranları Fineman-Ross (F-R) ve Kelen-Tüdös (K-T) lineer metotlarıyla ve lineer olmayan değişkenlerdeki hata metodu modeli bilgisayar programı RREVM ile hesaplandı. Kopolimerlerin FTIR, 1H-NMR ve 13C-NMR spektrumları yorumlandı. Polimerlerin yumuşama sıcaklıkları DSC ile ve termal kararlılıkları TGA ile belirlendi.
dc.description.abstractIn this study, N,N?-dipropionitrile methacrylamide (DPMAAm) monomer was synthesized by the reaction of N,N?-iminodipropionitrile with methacryloyl chloride at 0-5 oC in the presence of triethylamine. The structure of monomer was characterized by, FTIR, 1H-NMR and 13C-NMR spectroscopic techiques.Copolymers having various DPMAAm with styrene (St) and p-chloromethylene styrene (ClM-St) contents were prepared in 1,4-dioxane solvent using %1 AIBN as initiator at 70 oC with the conversions below of %10. The copolymer composition were determined by elemental analysis. Monomer reactivity ratios were calculated both Finemann-Ross (F-R) and Kelen-Tüdös (K-T) lineer methods, and a nonlinear error invariable model method with the computer program RREVM. The FTIR, 13C-NMR and 1H-NMR spectra of the copolymers were discussed. The glass transition temperature of polymers were investigated by DSC and also thermal stabilities were studied by TGA.en_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleNitril grupları içeren metakrilamit polimerlerinin sentezi ve karakterizasyonu
dc.title.alternativeSynthesis and characterization of nitrile group containing methacrylamide polymers
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentKimya Ana Bilim Dalı
dc.subject.ytmPolyamide
dc.subject.ytmPolymer materials
dc.subject.ytmPolymeric structures
dc.subject.ytmPolymethyl methacrylate
dc.subject.ytmStyrene
dc.subject.ytmPolymethacrylate
dc.subject.ytmPolymers
dc.identifier.yokid400806
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityBOZOK ÜNİVERSİTESİ
dc.identifier.thesisid290963
dc.description.pages75
dc.publisher.disciplineDiğer


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