dc.contributor.advisor | Sağlam, Ertuğrul Gazi | |
dc.contributor.author | Tutsak, Özgür | |
dc.date.accessioned | 2021-05-07T08:24:25Z | |
dc.date.available | 2021-05-07T08:24:25Z | |
dc.date.submitted | 2017 | |
dc.date.issued | 2018-08-06 | |
dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/596411 | |
dc.description.abstract | Bu çalışmada ferrosenil ditiyofosfonik asitlerin (Fc(RO)P(S)S-NH4+; R= -(CH2)3-C6H5), FcL1; R= -CH-(Ph)(C2H5), FcL2; R= -CH2-CH2-CH-(CH3)2, FcL3; R= -CH-(C2H5)2, FcL4) amonyum tuzları ve bu tuzların metal katyonları ile kompleksleri elde edildi ([M(Fc(RO)P(S)S)2]n, n= 1, M= Ni2+ ; n= 2, Cd2+, Hg2+ ; R= -(CH2)3-C6H5), [Ni(FcL1)2]; R= -CH-(Ph)(C2H5), [Ni(FcL2)2]; R= -CH2-CH2-CH-(CH3)2, [Ni(FcL3)2]; R= -CH-(C2H5)2, [Ni(FcL4)2]). Yeni ferrosenil Ditiyofosfonik asitler, Ferrosenil Lawesson reaktifinin alkollerle reaksiyonundan sentezlendi. Bu asitlerden amonyum tuzları izole elde edildi. Amonyum tuzlarından dört koordinasyonlu yeni kare düzlem nikel kompleksleri sentezlendi. Nikel komplekslerinden ayrıca piridin (Py) ile yeni oktahedral (altı koordinasyonlu) kompleksleri sentezlendi ([Ni(Fc(RO)P(S)S)2Py2]; [Ni(FcL1)2(Py)2], [Ni(FcL22(Py)2], [Ni(FcL3)2(Py)2] ve [Ni(FcL4)2(Py)2]).Ferrosenil ditiyofosfonik asit tuzlarının ve komplekslerinin yapıları element analizi, MS, FT-IR, Raman spektroskopisiyle beraber ayrıca 1H-, 13C-, 31P-NMR analiz tekniği ile aydınlatıldı. [Ni(FcL3)2] kompleksinin yapısı X-ışınları kırınım metresiyle aydınlatıldı.Anahtar Kelimeler: Ferrosenilditiyofosfonat, Ferrosenilditiyofosfonat kompleksleri, heterobimetalic kompleks, Ferrosenil Lawesson Reaktifi, Lawesson Reaktifi. | |
dc.description.abstract | In this work, some ferrocenyl dithiophosphonic acids were synthesised (Fc(RO)P(S)S-NH4+; R= -(CH2)3-C6H5), FcL1; R= -CH-(Ph)(C2H5), FcL2; R= -CH2-CH2-CH-(CH3)2, FcL3; R= -CH-(C2H5)2, FcL4) as an ammonium derivates. The new complexes of ferrocenyl dithiophosphonates were synthesised via the reaction of metal cations with ammonium dithiophosphonates ([M(Fc(RO)P(S)S)2]n, n= 1, M= Ni2+ ; n= 2, Cd2+, Hg2+ ; R= -(CH2)3-C6H5), [Ni(FcL1)2]; R= -CH-(Ph)(C2H5), [Ni(FcL2)2]; R= -CH2-CH2-CH-(CH3)2, [Ni(FcL3)2]; R= -CH-(C2H5)2, [Ni(FcL4)2]).In the first step, the ferrocenyl dithiophosphonic acids were obtained by means of reaction of between Ferrocenyl Lawesson reagent some alcohols. Then these acids were obtained their ammonium salts. Two octahedral nickel complexes were also synthesized by the reaction of some new square planar with pyridine ([Ni(Fc(RO)P(S)S)2Py2]; [Ni(FcL1)2(Py)2], [Ni(FcL22(Py)2], [Ni(FcL3)2(Py)2] ve [Ni(FcL4)2(Py)2]).The complexes ve ligands were characterized by elemental analysis, 1H-, 13C-, 31P-NMR, MS, FTIR. [Ni(FcL3)2] complex was elucidated by X-ray crystallography.Key words: Ferrocenyl dithiophosphonate, ferrocenyl dithiophosphonate complexes, heterobimetalic complex, Ferrocenyl Lawesson's Reagent. | en_US |
dc.language | Turkish | |
dc.language.iso | tr | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.rights | Attribution 4.0 United States | tr_TR |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Kimya | tr_TR |
dc.subject | Chemistry | en_US |
dc.title | 1,3,2,4 ditiyafosfetan-2,4 disülfür`lerin katılma reaksiyonları ürünlerinin sentezi ve yapılarının aydınlatılması | |
dc.title.alternative | Synthesis and structural investigation of addition reaction's yields of 1,3,2,4-dithiadiphosphetane-2,4-disulfide | |
dc.type | masterThesis | |
dc.date.updated | 2018-08-06 | |
dc.contributor.department | Kimya Ana Bilim Dalı | |
dc.identifier.yokid | 10148155 | |
dc.publisher.institute | Fen Bilimleri Enstitüsü | |
dc.publisher.university | BOZOK ÜNİVERSİTESİ | |
dc.identifier.thesisid | 463692 | |
dc.description.pages | 251 | |
dc.publisher.discipline | Diğer | |