Norbornadien ve benzofuran dimerlerinin sentezi ve diels-alder tepkimeleri
dc.contributor.advisor | Daştan, Arif | |
dc.contributor.author | Dalkiliç, Erdin | |
dc.date.accessioned | 2020-12-03T13:34:48Z | |
dc.date.available | 2020-12-03T13:34:48Z | |
dc.date.submitted | 2008 | |
dc.date.issued | 2018-08-06 | |
dc.identifier.uri | https://acikbilim.yok.gov.tr/handle/20.500.12812/50594 | |
dc.description.abstract | Benzofuran molekülünün dimerleri sentezlendi. Elde edilen dimerik dienlerin Diels-Alder tepkimeleri incelendi ve ilgili dienlerin siklokatılma tepkimesine karşı reaktivitesinin çok düşük olduğu belirlendi.Çalışmanın diğer kısmında norbornadien'in dimerleri sentezlendi. Karışım halindeki dimerik dienler'in PTAD ve TCNE ile Diels-Alder reaksiyonlarıyla ilgili siklokatılma ürünleri elde edildi.Son olarakta 2,3-dibromnorbornadien'in oda sıcaklığı ve yüksek sıcaklıktaki brominasyon reaksiyonu incelendi. Ürünlerin oluşum mekanizmaları tartışıldı2008, 85 sayfaAnahtar Kelimeler: Benzofuran, Norbornadien, Dimerizasyon, Diels-Alder Tepkimesi, Brominasyon. | |
dc.description.abstract | Dimers of benzofuran were synthesized. Diels-Alder reactions of dimeric diens were investigated. It was found that dienes had a very low reactivity for cycloaddition reactions.Along side this, dimers of norbornadien were synthesized. A mixture of dimeric diens were found to give Diels-Alder reactions with PTAD and TCNE to form the related cycloaddition products.Bromination reaction of 2,3-bromonorbornadien was investigated at room temperature and high temperature. The reaction mechanism of the products was discused.2008, 85 pagesKeywords: Benzofuran, Norbornadiene, Dimerisation, Diels-Alder Reactions, Bromination | en_US |
dc.language | Turkish | |
dc.language.iso | tr | |
dc.rights | info:eu-repo/semantics/openAccess | |
dc.rights | Attribution 4.0 United States | tr_TR |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Kimya | tr_TR |
dc.subject | Chemistry | en_US |
dc.title | Norbornadien ve benzofuran dimerlerinin sentezi ve diels-alder tepkimeleri | |
dc.title.alternative | Synthesis of norbornadiene and benzofuran's dimersand their diels-alder reactions | |
dc.type | masterThesis | |
dc.date.updated | 2018-08-06 | |
dc.contributor.department | Kimya Anabilim Dalı | |
dc.identifier.yokid | 319710 | |
dc.publisher.institute | Fen Bilimleri Enstitüsü | |
dc.publisher.university | ATATÜRK ÜNİVERSİTESİ | |
dc.identifier.thesisid | 232356 | |
dc.description.pages | 85 | |
dc.publisher.discipline | Diğer |