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dc.contributor.advisorÖzler, Mehmet Ali
dc.contributor.authorTürkmen, Hayati
dc.date.accessioned2020-12-29T13:22:41Z
dc.date.available2020-12-29T13:22:41Z
dc.date.submitted2000
dc.date.issued2018-08-06
dc.identifier.urihttps://acikbilim.yok.gov.tr/handle/20.500.12812/424799
dc.description.abstractÖZET Bu çalışmada, N-(2-piridil)aminoglioksim(PYGH2),N-(4metil-2-piridil)aminoglioksim (MPYGH2), N,N1-bis(2rpiridil)diaminoglioksim(BPYGH2 ) ve N^-bis^-metil^-piridil) diaminoglioksim (BMPYGH2) sentezlendi. Daha sonra bunlann bazı geçiş metalleri ile yapmış oldukları kompleksler üzerinde çalışıldı. A «rt-kloroglioksimin alkollü çözeltisi üzerine 2-amino pridinin ve 2-amino-4-metil pridinin alkollü çözeltileri ilave edildiğinde PYGH2 ve MPYGH2; alkollü anti-dikloro üzerine yine 2-amno pridin ve 2-amino-4-metilpridin çözeltisi ilave edildiğinde BPYGH2 ve BMPYGH2 elde edildi. Alkollü ortamda çözünmüş olan PYGH2, MPYGH2,BPYGH2 ve BMPYGH2 ve Ni(H), Co(II), Cu(II) iyonlannın alkollü çözeltisi ilave edildiğinde 3 civarında olan pH, %1 NaOH çözeltisi ile 5,5-6'ya ayarlanarak kompleksler çöktürüldü. Sonuç olarak dört yeni ligand ve 12 kompleks sentezlenmiş; FT-IR, 'H-NMR ve Elementel analizleri yapılarak yapılan aydınlatılmaya çalışıldı.
dc.description.abstractSUMMARY In this study, N-(2-pyridyl) aminoglioxime (PYGH2), N-(4-methyl-2-pyridyl) amino glioxime (MPYGH2), N,N1-Bis(2-pyridyl) diamino glioxime(BPYGH2) and N,N1(4-methyl- 2-pyridyl)diamino glioxime (BMPYGH2) were synthesized and their complexes with some transistion metals were examined. When 2-amino pyridine and 2-amino-4methyl pyridine which were soluted in ethanol were added to the alcolic anti-chloroglyoxime solution, PYGH2 and MPYGH2 were obtained. As the same way when those solutions were added to the alcolic anti-dichloroglioximes, BPYGH2 and BMPYGH2 were obtained as crystalline structure. After pH adjustment of the solution with %1 NaOH, Cu (II), Co(II), Ni(II) complexes of BPYGH2 and BMPYGH2 were obtained. As a result, four ligands and twelve complexes were isolated. FT-IR, ^-NMR and Elemental analyses have been used to elucidate the structure of ligands and complexes.en_US
dc.languageTurkish
dc.language.isotr
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.rightsAttribution 4.0 United Statestr_TR
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectKimyatr_TR
dc.subjectChemistryen_US
dc.titleHeterosiklik vic-dioksimlerin sentezi ve geçiş metalleri ile yapmış oldukları homo- ve hetero-polinükleer komplekslerinin sentezi
dc.title.alternativeSynthesis of heterocyclic vic-dioximes and their homo- and hetero-nuclear complexes with some transition metals
dc.typemasterThesis
dc.date.updated2018-08-06
dc.contributor.departmentDiğer
dc.subject.ytmPyridine
dc.subject.ytmSynthesis
dc.subject.ytmVic-dioximes
dc.subject.ytmTransition metals
dc.subject.ytmOximes
dc.identifier.yokid102197
dc.publisher.instituteFen Bilimleri Enstitüsü
dc.publisher.universityMUĞLA ÜNİVERSİTESİ
dc.identifier.thesisid97756
dc.description.pages32
dc.publisher.disciplineDiğer


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