1-amino-5-benzoil-4-fenil-1H-primidin-2-on ligandının Co(II), Ni(II) ve Cu(II) komplekslerinin sentezi ve karakterizasyonu

Abstract

ÖZET Yüksek Lisans Tezi 1-AMİNO-5-BENZOİL-4-FENİL-1H-PİRİMİDİN-2-ON LİGANDININ Co(II), Ni(II) ve Cu(Tl) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU Mehmet GULCAN Fırat Üniversitesi Fen Bilimleri Enstitüsü Kimya Anabilim Dalı 2003, Sayfa: 38 l-Amino-5-Benzoil-4-Fenil-lH-Pirimidin-2-On ligandı, literatürde verildiği gibi furandion ile asetofenon semikarbazonun reaksiyonundan elde edilen amino-alkil pirimidinonun hidrolizi sonucu elde edildi. Bu ligandın kompleksleri Co(II), Ni(II) ve Cu(II) asetatları ile hazırlandı. Ligand ve kompleklerin yapılan Elementel Analiz, İR, Mağnetik Süsseptibilite, Kondüktometri ve 'H-NMR teknikleriyle ile karakterize edildi. Anahtar Kelimeler: l-Amino-5-Benzoil-4-Fenil-lH-Pirimidin-2-On Ligandı ve Co(II), Ni(II) ve Cu(II) Kompleksleri. II

ABSTRACT Master Thesis SYNTHESIS AND CHARACTERIZATION OF 1-AMINO-5-BENZOYL-4-PHENYL- 1H-PYRIMIDINE-2-ONE LIGAND AND Co(H), Ni(H), AND Cu(n) COMPLEXES Mehmet GÜLCAN Fırat University Graduate School of Natural and Applied Sciencies. Department of Chemistry 2003, Page: 38 l-Amino-5-Benzoyl-4-Phenyl-lH-Pyrimidine-2-One ligand was obtained as given in the literature from result of 5-Benzoil-l-(methylphenylmethyleneamino)-4-Phenyl-lH- Pyrimidine-2-One hydrolysis obtained from reaction of furandion and acetophenon semicarbazone. The complexes of this ligand were prepared with Co(II), Ni(II) and Cu(II) acetats. The structures of ligand and complexes were characterized by Elementel Analysis, IR, Magnetic Susceptibility, Conductivimetry and 'H-NMR techniques. Key Words : l-Amino-5-Benzoyl-4-Phenyl-lH-Pyrimidine-2-One Ligand and Co(II), Ni(II) and Cu(II) Complexes. m