Yeni tiyoüre türevi ligand ve metal komplekslerinin sentezlenmesi ve karakterizasyonu

Abstract

Bu tez çalısmasın da, N-(dietilkarbamotiyoil)-2,2-difenilasetamid, N-(di-npropilkarbamotiyoil)-2,2-difenilasetamid, N-(di-n-bütilkarbamotiyoil)-2,2-difenilasetamid, N-(di-n-hekzilkarbamotiyoil)-2,2-difenilasetamid, N-(difenilkarbamo tiyoil)-2,2-difenilasetamid ve N-(morfolin-4-tiyoil)-2,2-difenilasetamid ligandları ile bunlarınbis(N-(dietilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(dietilkarba motiyoil)-2,2-difenilasetamid)bakır(II), bis(N-(di-n-propilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(di-n-propilkarbamotiyoil)-2,2-difenilaset amid) bakır(II),bis(N-(di-n-bütilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(di-n-bütilkarbamotiyoil)-2,2-difenilasetamid) bakır(II), bis(N-(di-n-hekzilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(di-n-hekzilkarba motiyoil)-2,2-difenilasetamid)bakır(II), bis(N-(difenilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(difenilkarbamotiyoil)-2,2-difenilasetamid) bakır(II), bis(N-(morfolin-4-tiyoil)-2,2-difenilasetamid) nikel(II) ve bis(N-(morfolin-4-tiyoil)-2,2-difenilasetamid) bakır(II)kompleksleri sentezlendi. Sentezlenen bilesiklerin karakterizasyonları, elementelanaliz, FT-IR spektroskopisi ve 1H-NMR spektroskopisi yöntemleri ile yapıldı.Sentezlenen N-(dietilkarbamotiyoil)-2,2-difenilasetamid, N-(di-n-propilkarbamotiyoil)-2,2-difenilasetamid, bis(N-(dietilkarbamotiyoil)-2,2-difenilasetamid) nikel(II),bis(N-(dietilkarbamotiyoil)-2,2-difenilasetamid) bakır(II), bis(N-(di-n-propilkarbamotiyoil)-2,2-difenilasetamid) nikel(II), bis(N-(di-n-propilkarbamotiyoil)-2,2-difenilasetamid) bakır(II), bis(N-(di-n-bütilkarbamotiyoil)-2,2-difenilasetamid) nikel(II),bis(N-(di-n-hekzilkarbamotiyoil)-2,2-difenilasetamid) bakır(II) ve bis(N-(morfolin-4-tiyoil)-2,2-difenilasetamid) nikel(II) bilesiklerinin kristal yapıları ise X-ısınları tekkristal kırınım teknigi ile aydınlatıldı.

In this thesis study, N-(diethylcarbamothioyl)-2,2-diphenylacetamide, N-(di-npropylcarbamothioyl)-2,2-diphenylacetamide, N-(di-n-buthylcarbamothioyl)-2,2-diphenylacetamide, N-(di-n-hexylcarbamothioyl)-2,2-diphenylacetamide, N-(diphenylcarbamothioyl)-2,2-diphenylacetamide, N-(morpholine-4-carbonothioyl)-2,2-diphenylacetamide ligands and their complexes which are bis-[N-(diethylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(diethylcarba mothioyl)-2,2-diphenylacetamido]copper(II), bis-[N-(di-n-propylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(di-n-propylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(di-nbuthylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(di-n-buthylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(di-n-hexylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(di-n-hexylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(diphenylcarbamothioyl)-2,2-diphenylacetamido]nickel(II), bis-[N-(diphenylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(morpholine-4-carbonothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(morpholine-4-carbonothioyl)-2,2-diphenylacetamido] copper(II) complexes, were synthesized.Synthesized compounds characterized by using elemental analysis, FT-IRspectroscopy and 1H-NMR spectroscopy techniques. The crystal structure of N-(diethylcarbamothioyl)-2,2-diphenylacetamide, N-(di-n-propylcarbamothioyl)-2,2-diphenylacetamide, bis-[N-(diethylcarbamothioyl)-2,2-diphenylacetamido] nickel(II),bis-[N-(diethylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(di-n-propylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(di-n-propylcarbamothioyl)-2,2-diphenylacetamido] copper(II), bis-[N-(di-n-buthylcarbamothioyl)-2,2-diphenylacetamido] nickel(II), bis-[N-(di-n-hexylcarbamothioyl)-2,2-diphenylacetamido]copper(II), and bis-[N-(morpholine-4-carbonothioyl)-2,2-diphenylacetamido]nickel(II) clarified by the X-ray single crystal diffraction technique.